Purification of gases using nanoporous inorganic membranes.

The application of membranes has gained acceptance in the chemical and process industries for separation and purification for over three decades and is currently being practiced for natural gas processing, waste water treatment among others. A crack-free composite membrane was employed in this paper. Scanning electron microscopy (SEM) observation was carried out to characterize the membrane. The operational parameters such as feed flow rate, permeation pressure, permeation temperature, kinetic diameter and gas molecular characteristics are examined at 25C to 450C and 0.05 to 1.0 barg feed pressure. The performance of gas selectivity is also provided. Separation factor of 2.554 was obtained for H2/CO2 at 450C and 0.8 barg. Activation energies of 1.0 and 0.42 kJ/mol were also obtained for H2 and CO2/CO/H2 gas mixtures at 1.0 barg

Proximate analysis of the fruit Azanza garckeana (“Goron Tula”)

The chemical composition and some selected metal ions of the fruit Azanza garckeana locally called “Goron Tula” obtained from different parts of Tula in Kaltungo Local Government Area of Gombe State were analysed. The chemical compositions determined showed a carbohydrate content in the range 49-56%; ascorbic acid 285.5-308.5mg/50g; fat content 0.0541-0.0543%; and starch while the selected metals Fe, Mg, Ca, and Mn were in the range 120-140μg/g, 1700-2300μg/g, 350-450μg/g, and 71-101μg/g respectively.Key words: Azanza Garckeana fruit, proximate analysis, metal ions, carbohydrate content, ascorbic acid. Ascorbic acid, Azanza Garckeana fruit, carbohydrate content, proximate analysis, metal ions

Application of spectral analysis to determine the magnetic source depths in ibarapa district, oyo state, sw nigeria

The method of spectral analysis was applied to the total aeromagnetic intensity data covering the district of Ibapara, located on the Nigeria Basement Complex in Oyo State, SW Nigeria. Prior to the spectral analysis, inclined magnetisation was converted to vertical, reduced to the pole and filtered out in order to more correctly reflect spatial location and morphology of magnetic sources over geological bodies, and enhance the effects of shallower sources over deeper ones. The data was divided into blocks and sub-blocks, and was spectrally analysed for the depths to the deep- and shallow-seated magnetic sources. The Curie-point-depths computed from these depths vary between 20.8 and 32.73 km, indicating that the magnetized basement rocks are at different elevations and are probably block faulted. The correlation of shallow Curie-point-depth with the Older Granites inferred that the low Curie-point-depth is due to magmatic intrusion in the highly deformed migmatite unit, the main geologic unit. The surface heat flows derived from the Curie-point-depths vary between 40.82 and 62.84 with a mean of 50.10 mW m-2, with areas having high surface heat flow presumed to be areas of recent intrusions where the elevated heat has transformed appropriate minerals to sapphire, tourmaline and aquamarine. Correlations of the surface heat flows and the average geothermal gradients on one hand and the Curie-point-depth on the other, unlike global compilation, yielded close empirical relations that are attributed to homogeneous geology of the area

Physicochemical and Heavy Metals Characteristics of Soil from Three Major Dumpsites in Ilorin Metrpolis, North Central Nigeria

Impact of waste disposal and management is a worldwide phenomenon leading to health impact most especially in underdeveloped and developing world. This study was undertaken to assess the major contaminants in some municipal waste disposal sites and the prospective impact to the surrounding domestic water supply source as well as the impact on the health of the people in the city. This is carried out by studying variousphysico-chemical parameters of soil which were collected from three municipal dump locations namely; Ita-Amodu, Sawmill garage and Kuntu areas in Ilorin metropolis, Kwara State Nigeria. The geochemistry of the dumpsites were studied with respect to important parameters such as pH, electrical conductivity, temperature, sulphates, chlorides, nitrates, moisture content, organic matter and heavy metals having the following constituents present in its composition- Cadmium (Cd), Lead (Pb), Zinc (Zn), Iron (Fe), and Copper (Cu). The study revealed that the three different soils samples: “(A) Ita-Amodu”, “(B) Sawmill Garage”, and “(C) Kuntu”) have pH of 7.1, 7.2 and 6.8, respectively. Temperature of 24.2, 26.4, and 28.0 oC, Organic matter compositions of 0.95%, 0.73%, and 1.14%. The Moisture contents were 3.93%, 2.89%, and 3.48% respectively. The chloride  contents of the samples was found to be 31.76 mg/L, 48.98 mg/L, and 91.63 mg/L, while nitrates were found to be 0.10 mg/L, 0.06, mg/L and 0.23mg/L, with a sulphate values of 1.96 mg/L, 2.35 mg/L, and 2.14 mg/L. The conductivities were 1.79 μs/cm, 2.23 μs/cm, and 1.15 μs/cm respectively. Heavy metal analysis from the waste soil were found to contained copper (Cu) - 0.03 mg/L, 0.028 mg/L, and 0.031 mg/L, zinc (Zn) - 0.04, mg/L 0.009 mg/L, and 0.066 mg/L), cadmium (Cd) - 0.516 mg/L, 0.62, mg/L and 0.048 mg/L), Lead (Pb) - 0.063 mg/L, 0.07 mg/L, and 0.056 mg/L), and iron (Fe) -0.518 mg/L, 0.62 mg/L, and 0.190 mg/L. Keywords: Dumpsites, Heavy metals, Ilorin, Moisture contents, Nitrates

Convergence of Path and Approximation of Common Element of Null Spaces of Countably Infinite Family of m

We prove path convergence theorems and introduce a new iterative sequence for a countably infinite family of m-accretive mappings and prove strong convergence of the sequence to a common zero of these operators in uniformly convex real Banach space. Consequently, we obtain strong convergence theorems for a countably infinite family of pseudocontractive mappings. Our theorems extend and improve some important results which are announced recently by various authors

Obstetric Characteristics and Management of Patients with Postpartum Psychosis in a Tertiary Hospital Setting

Background. Postpartum psychosis is the most severe and uncommon form of postnatal affective illness. It constitutes a medical emergency. Acute management emphasizes hospitalization to ensure safety, antipsychotic medication adherence, and treatment of the underlying disorder. Objective. The aim of the study was to determine the obstetric characteristics and management of patients with postpartum psychosis in a tertiary centre in North-Western Nigeria. Methodology. This was a 10-year retrospective study. Records of the patients diagnosed with postpartum psychosis from January 1st, 2002, to December 31st, 2011, were retrieved and relevant data extracted and analyzed using the SPSS for Windows version 16.0. Results. There were 29 cases of postpartum psychosis giving an incidence of 1.1 per 1000 deliveries. The mean age of the patients was 20.6 ± 4 years. Twelve (55%) were primiparae, 16 (72.7%) were unbooked, and 13 (59%) delivered at home. All had vaginal deliveries at term. There were 12 (52.2%) live births, and 11 (47.8%) perinatal deaths and the fetal sex ratio was equal. The most common presentation was talking irrationally. Conclusion. There is need for risk factor evaluation for puerperal psychosis during the antenatal period especially in primigravidae and more advocacies to encourage women to book for antenatal care in our environment

The incidence, pattern and management of sexual assault in a tertiary hospital in North-western Nigeria

Background: Sexual assault is any sexual act performed by one person on another without the person’s consent or on a victim who is incapable of giving consent. It is a violation of basic human rights, a gender-based issue and a violent crime against both the individual and the society. The objectives of the study were to determine the incidence, pattern and management of sexual assault in Usmanu Danfodiyo University Teaching Hospital, Sokoto, Nigeria.Methods: This was a 10 - year retrospective study. Case records of sexual assault from 1st January, 2007 to 31st December, 2016 were retrieved and relevant data extracted and analyzed using the SPSS for windows version 20.0Results: The incidence of sexual assault was 0.8%. Majority, 88 (85.4%) occurred in children and adolescents. Peno-vaginal penetration was the most common form of assault 65 (63.1%) and the assailants were known to the victims in 74 (71.9%) of the cases. Involvement of psychiatrists/psychologists in the management of the victims was poor as psychiatrists were involved in only 13 (12.6%) of the cases. Most of the victims were lost to follow up.Conclusions: Sexual assaults occurred mostly in children and adolescents in this study. Increased public awareness and preventive interventions are required especially among the at-risk age groups to enhance their safety. Training of relevant persons in the institution to offer counselling to the victims is recommended as referral for psychiatrists’ consultation was poor. It is important to institute a good tracking system to follow up the victims as most are lost to follow up.